Make sure your controllers are being detected in the Device Manager and ensure you assigned both controllers. Your PSMove should light up Red before you start VRchat.
I can confirm that it does work in VRChat but the difference is I used a Kinect One and have head options set to OFF and use iVRy_SteamVR APP (Mobile phone) for head-tracking. Although my results were botched since I only have one PSMove atm.
If your calibration is fine after testing then you no longer have to focus in that area. It has to do with Keybindings/Device manager. Keep messing around with the options and you’ll eventually get it to work I’m sure!
Hope you come back here to report your experience after you get it working!